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Webb Discovers Methane, Carbon Dioxide in Atmosphere of K2-18 b

Illustration of a planet and its cool red dwarf star. In the foreground on the right is the planet, which fills most of the frame. The planet is various shades of blue, with wisps of white scattered throughout. The left edge of the planet (the side facing the star) is lit, while the rest is in shadow. In the background at the lower left is the star, which appears smaller. The star has a bright red glow. Also in the background is another planet, which appears as a small crescent. The black background of space is speckled with a few small stars.
This illustration shows what exoplanet K2-18 b could look like based on science data. K2-18 b, an exoplanet 8.6 times as massive as Earth, orbits the cool dwarf star K2-18 in the habitable zone and lies 120 light years from Earth. A new investigation with NASA’s James Webb Space...
Credits: Illustration: NASA, ESA, CSA, Joseph Olmsted (STScI); Science: Nikku Madhusudhan (IoA)

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A new investigation with NASA’s James Webb Space Telescope into K2-18 b, an exoplanet 8.6 times as massive as Earth, has revealed the presence of carbon-bearing molecules including methane and carbon dioxide. Webb’s discovery adds to recent studies suggesting that K2-18 b could be a Hycean exoplanet, one which has the potential to possess a hydrogen-rich atmosphere and a water ocean-covered surface.

The first insight into the atmospheric properties of this habitable-zone exoplanet came from observations with NASA’s Hubble Space Telescope, which prompted further studies that have since changed our understanding of the system.

K2-18 b orbits the cool dwarf star K2-18 in the habitable zone and lies 120 light-years from Earth in the constellation Leo. Exoplanets such as K2-18 b, which have sizes between those of Earth and Neptune, are unlike anything in our solar system. This lack of equivalent nearby planets means that these ‘sub-Neptunes’ are poorly understood, and the nature of their atmospheres is a matter of active debate among astronomers.

Image: Artist Concept-Exoplanet K2-18 b

Illustration of a planet and its cool red dwarf star. In the foreground on the right is the planet, which fills most of the frame. The planet is various shades of blue, with wisps of white scattered throughout. The left edge of the planet (the side facing the star) is lit, while the rest is in shadow. In the background at the lower left is the star, which appears smaller. The star has a bright red glow. Also in the background is another planet, which appears as a small crescent. The black background of space is speckled with a few small stars.
This illustration shows what exoplanet K2-18 b could look like based on science data. K2-18 b, an exoplanet 8.6 times as massive as Earth, orbits the cool dwarf star K2-18 in the habitable zone and lies 120 light years from Earth. A new investigation with NASA’s James Webb...
Illustration: NASA, ESA, CSA, Joseph Olmsted (STScI); Science: Nikku Madhusudhan (IoA)

The suggestion that the sub-Neptune K2-18 b could be a Hycean exoplanet is intriguing, as some astronomers believe that these worlds are promising environments to search for evidence for life on exoplanets.

"Our findings underscore the importance of considering diverse habitable environments in the search for life elsewhere," explained Nikku Madhusudhan, an astronomer at the University of Cambridge and lead author of the paper announcing these results. "Traditionally, the search for life on exoplanets has focused primarily on smaller rocky planets, but the larger Hycean worlds are significantly more conducive to atmospheric observations."

The abundance of methane and carbon dioxide, and shortage of ammonia, support the hypothesis that there may be a water ocean underneath a hydrogen-rich atmosphere in K2-18 b. These initial Webb observations also provided a possible detection of a molecule called dimethyl sulfide (DMS). On Earth, this is only produced by life. The bulk of the DMS in Earth’s atmosphere is emitted from phytoplankton in marine environments.

Image: Spectra of K2-18 b

A graphic titled “Exoplanet K2-18 b: Atmosphere Composition.” The graphic shows the spectra of the exoplanet K2-18 b from NIRISS and NIRSpec in the form of a graph, with the vertical y-axis labeled as Amount of Light Blocked and the horizontal axis labeled as Wavelength of Light (microns). The spectra is plotted as dots with vertical short vertical lines across the plot, with the best-fit model as a blue jagged white line.There are green, yellow and light blue vertical columns of varying thicknesses scattered across the plot indicating where variations in the line represent the presence of methane, carbon dioxide, and dimethyl sulfide, respectively. Behind the graph is an illustration of the planet and star. The planet is large fuzzy blue-ish sphere off to the right, taking up half of the background. The red star is smaller at the bottom left of the entire graphic.
Spectra of K2-18 b, obtained with Webb’s NIRISS (Near-Infrared Imager and Slitless Spectrograph) and NIRSpec (Near-Infrared Spectrograph) displays an abundance of methane and carbon dioxide in the exoplanet’s atmosphere, as well as a possible detection of a molecule called...
Illustration: NASA, ESA, CSA, Ralf Crawford (STScI), Joseph Olmsted (STScI); Science: Nikku Madhusudhan (IoA)

The inference of DMS is less robust and requires further validation. “Upcoming Webb observations should be able to confirm if DMS is indeed present in the atmosphere of K2-18 b at significant levels,” explained Madhusudhan.

While K2-18 b lies in the habitable zone, and is now known to harbor carbon-bearing molecules, this does not necessarily mean that the planet can support life. The planet's large size — with a radius 2.6 times the radius of Earth — means that the planet’s interior likely contains a large mantle of high-pressure ice, like Neptune, but with a thinner hydrogen-rich atmosphere and an ocean surface. Hycean worlds are predicted to have oceans of water. However, it is also possible that the ocean is too hot to be habitable or be liquid.

"Although this kind of planet does not exist in our solar system, sub-Neptunes are the most common type of planet known so far in the galaxy," explained team member Subhajit Sarkar of Cardiff University. “We have obtained the most detailed spectrum of a habitable-zone sub-Neptune to date, and this allowed us to work out the molecules that exist in its atmosphere.”

Characterizing the atmospheres of exoplanets like K2-18 b — meaning identifying their gases and physical conditions — is a very active area in astronomy. However, these planets are outshone — literally — by the glare of their much larger parent stars, which makes exploring exoplanet atmospheres particularly challenging.

The team sidestepped this challenge by analyzing light from K2-18 b's parent star as it passed through the exoplanet's atmosphere. K2-18 b is a transiting exoplanet, meaning that we can detect a drop in brightness as it passes across the face of its host star. This is how the exoplanet was first discovered in 2015 with NASA’s K2 mission. This means that during transits a tiny fraction of starlight will pass through the exoplanet's atmosphere before reaching telescopes like Webb. The starlight's passage through the exoplanet atmosphere leaves traces that astronomers can piece together to determine the gases of the exoplanet's atmosphere.

"This result was only possible because of the extended wavelength range and unprecedented sensitivity of Webb, which enabled robust detection of spectral features with just two transits," said Madhusudhan. "For comparison, one transit observation with Webb provided comparable precision to eight observations with Hubble conducted over a few years and in a relatively narrow wavelength range."

"These results are the product of just two observations of K2-18 b, with many more on the way,” explained team member Savvas Constantinou of the University of Cambridge. “This means our work here is but an early demonstration of what Webb can observe in habitable-zone exoplanets.”

The team’s results were accepted for publication in The Astrophysical Journal Letters.

The team now intends to conduct follow-up research with the telescope's MIRI (Mid-Infrared Instrument) spectrograph that they hope will further validate their findings and provide new insights into the environmental conditions on K2-18 b.

"Our ultimate goal is the identification of life on a habitable exoplanet, which would transform our understanding of our place in the universe," concluded Madhusudhan. "Our findings are a promising step towards a deeper understanding of Hycean worlds in this quest."

The James Webb Space Telescope is the world's premier space science observatory. Webb is solving mysteries in our solar system, looking beyond to distant worlds around other stars, and probing the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and the Canadian Space Agency.

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Last Updated
Aug 28, 2025
Contact
Media

Laura Betz
NASA’s Goddard Space Flight Center
Greenbelt, Maryland
laura.e.betz@nasa.gov

Hannah Braun
Space Telescope Science Institute
Baltimore, Maryland

Bethany Downer
European Space Agency
Paris, France

Science Credit

Nikku Madhusudhan (IoA)